CEE 680 |
Spring 2020 |
Click on L# to
see full Overheads or P# to see printable version (2 slides/pg)
All classes are at 8AM Eastern Time unless otherwise indicated
Date |
Day |
Video |
L# |
P# |
Lecture |
Homeworks |
|
Notes |
22 Jan |
W |
I. Introduction·
Course
overview, administration, chemistry review |
|
Chapt 1 & 2 (SM1&2, P1&2) |
|
|||
22 Jan |
W |
·
Stoichiometry,
activity |
|
|
|
|||
24 Jan |
F | Z, E |
·
Kinetics theory
& data analysis |
|
|
|
||
27 Jan | M | Z, E |
·
Ionic Strength
Effects |
|
|
|
||
29 Jan |
W | Z, E |
·
Kinetics |
|
|
|||
29 Jan |
W | Z, E |
II. Acids and Bases
·
Definitions,
Nature and strength
|
|
(SM3, P3-8) |
|||
31 Jan | F | Z, E | ·
Equilibrium expressions
|
|
|
|
||
3 Feb
|
M | Z, E |
·
Analytical
Solutions
·
Use of
simplifying assumptions
|
|
|
|
||
5 Feb | W | Z, E |
·
Approximate vs.
exact
·
Types of
simplified solutions
|
|
|
|||
5 Feb | W | Z, E |
·
Summary of
special cases
|
|
|
10:10 | ||
7 Feb | F | Z, E |
·
Diprotic acids
·
graphical solutions
|
|
||||
10 Feb | M | Z, E |
·
graphical
solutions |
|
|
|||
12 Feb | W | Z, E |
·
graphical
solutions (cont.) |
|
||||
12 Feb | W | Z, E |
·
graphical
solutions (cont.) ·
Solutions of
two acids |
|
|
|
||
14 Feb | F | Z, E |
·
Thermodynamics
·
Temperature Effects
|
|
|
|||
17 Feb |
M | No Class, President's Day: UMass Holiday |
||||||
18 Feb | Tu | Z, E |
· Thermodynamics ·
Acid and Conjugate Base
|
|
|
Monday schedule |
||
19 Feb | W | No Class | ||||||
21 Feb | F | Z, E |
·
Titration
Curves ·
Buffers |
|
|
|
||
24 Feb | M | Z, E |
·
Titration
Curves (cont.)
·
Buffer
Intensity
|
|
10:10 | |||
26 Feb | W | Z, E | · MINEQL intro
·
Buffer
Intensity
|
|
Chapt. 7
(SM4, P9&10) |
|||
26 Feb | W | Z, E |
·
Alkalinity theory
·
Carbonates and Alk
|
|
||||
28 Feb | F | III. Dissolved Carbon Dioxide
·
Carbon cycle,
acid/base equil.
·
acid
precipitation
|
|
|
||||
Z, E | · Henry's Law, Pure water & pH |
|
|
10:10 | ||||
·
Alkalinity and CT
|
|
|
||||||
2 Mar | M | Z, E | · Closed sysemts |
|
|
|||
4 Mar | W | Z, E | · Open systems |
|
||||
4 Mar | W | Z, E |
·
Alk & Open systems
|
|
|
10:10 | ||
6 Mar | F | Z, E | IV. Coordination Chemistry
·
Definitions
& Hydrolysis
|
|
||||
9 Mar | M | Z, E |
·
Hydrolysis
& simple complexes
|
` |
Chapt. 8.1-8.6 (SM 6; P18) |
|
||
10 Mar | Tu |
|
First EXAM (5:30 PM; Elab 327) |
Through L#17
|
||||
11 Mar | W | Z, E |
|
|
·
Intro to MINEQL
|
|
|
|
11 Mar | W | Z, E |
·
Case Studies |
|
|
|
||
13 Mar | F | Z |
·
Classification
of metals |
|
|
|
||
UMass Spring Break |
||||||||
23 Mar | M | Zs, Z |
·
Case Studies:
EDTA |
|
|
|
||
25 Mar | W | Zs, Z |
·
Case Studies:
NTA ·
MINEQL problems |
|
|
|
||
25 Mar | W | Z | V. Precipitation and Dissolution
·
Composition of
natural waters
·
Solubility
products
|
|
Chapt. 8.7-8.15
(SM7; P11-14)
|
|
||
27 Mar | F | Zs, Z |
·
Solubility of
Metals
|
|
|
|||
30 Mar | M | Zs, Z |
·
Simple examples
|
|
|
|||
1 Apr | W | Zs, Z | 37
|
37
|
·
solubility of
various hydroxides
|
|||
1 Apr | W | Z |
|
10:10 |
||||
3 Apr | F | Zs, Z |
·
solubility of
carbonates
|
|
|
|
||
6 Apr | M | Zs, Z |
· Solubility of Carbonates
|
|
|
|
||
8 Apr | W | Zs, Z |
·
carbonates
& hydroxides |
|
|
|
||
8 Apr | W | Z |
·
carbonate
solubility: open systems |
|
|
|
||
10 Apr | F | Zs, Z |
·
Mixed
carbonate/hydroxide system |
Chapt. 9
(SM8, P19-23) |
|
|||
13 Apr | M | Zs, Z | 43 | 43 |
·
Precipitation, multiple solids phases & predominance diagrams
|
|
|
|
15 Apr | W | Zs, Z | ·
Cd Case
studies
|
|
|
|
||
|
|
·
mixed precipitates
|
|
|
|
|||
15 Apr | W | Z | 45 | 45 |
·
Mineral Formation
|
|
|
|
17 Apr | F | Zs, Z |
VI. Oxidation and Reduction
·
Oxidation
states
|
|
|
|||
20 Apr |
M | No Class: Patriot’s Day
|
||||||
22 Apr |
W | Zs, Z |
· Thermodynamic considerations
|
|
|
|||
|
|
· pe/pH diagrams
|
|
|
|
|||
24 Apr | F | Zs, Z |
· pe/pH diagrams
|
|
|
|
||
27 Apr | M | Zs, Z |
·
Redox Case StudiesI
|
|
|
|||
29 Apr | W | Zs, Z |
·
Lead Case Study
I
|
|
|
|
||
29 Apr | W | Z |
·
Lead Case Study
II
|
|
|
|
||
·
Arsenic I
· Arsenic II
·
Exam Prep
|
|
|
4 May |
Final Homework Due |
||
8 May | F | Semester Project Due |