This PDF
covers the following topics related to Physics of Electrochemical Processes :
The Electrical Double Layer, The Donnan model: the EDL in small pores, The EDL
for a planar surface: The Gouy-Chapman-Stern model, Ion volume effects in
electrochemical processes, The energy of an electrical double layer, The
interaction forces between colloidal particles, Solute Transport,
Electrokinetics, Heating and cooling in electrochemical systems, The relation
between the heat production rate and the free energy of an EDL, Combined mass
transport and chemical reactions, Reverse Osmosis and Nanofiltration,
Electrodialysis, The difference between Faradaic and non-Faradaic electrode
processes, Electrode Kinetics, Porous electrodes, Combined Faradaic and non-Faradaic
(capacitive) processes, Ion transport in bioelectrochemical systems, Transport
and reactions in electroactive biofilms, Redox reactions in environmental
chemistry, Overview of electrochemical water desalination, Numerical methods in
electrochemical processes, Experimental methods.
This
lecture note contains the following topics: introduction to Electrochemistry, Electrochemistry
Question bank, Corrosion and electrochemical process, Batteries and fuel cells,
Advanced materials, Nano materials and laboratory manual.
This lecture
note contains Redox Reactions and Faradays Laws, Equilibrium
Electrochemistry, Electrodes and Interfaces, Electrolytes, Dynamic
Electrochemistry, Industrial Electrochemistry, Energy Conversion and Storage,
Analytical Methods and Sensors, Corrosion and Corrosion Protection.
Author(s): Dr. Lorenz Gubler,
Electrochemistry Laboratory Paul Scherrer Institute Switzerland
This PDF covers the
following topics related to Solid-State Electrochemistry : Introduction,
Fundamentals, General aspects, SOFC geometries and assembly, Reactivity of
solids, Creep, demixing, and kinetic decomposition, Sintering, Polymer
Electrolyte Membrane Fuel Cells and Electrolyser Cells, Batteries, Selected
Additional Topics in Solid-State Electrochemistry.
This note explains the following topics: Nonfaradaic processes and
electrode-solution interface, Faradaic processes and rates of electrode
reactions, Mass-transfer controlled reactions, Basic Electrochemical
Thermodynamics, Electrochemical potential, Liquid junction potential, Selective
electrodes, Essentials of electrode reactions, Butler-Volmer model of electrode
kinetics, Implications of Butler-Volmer model for 1-step, 1-e process, Mass
transfer equation, Mixed migration and diffusion near an electrode,
Sampled-current voltammetry for quasireversible and irreversible electrode
reactions, Nernstian systems, Totally irreversible systems, Quasireversible
systems and Cyclic voltammetry.
Electrochemistry
has been undergoing significant transformations in the last few decades. It is
now the province of academics interested only in measuring thermodynamic
properties of solutions and of industrialists using electrolysis or
manufacturing batteries, with a huge gap between them. Topics covered includes:
Chromatographic, Polarographic and Ion-Selective Electrodes Methods for Chemical
Analysis of Groundwater, Electron Beam Ablation Phenomenon, Oxidation Chemistry
of Metal, Membrane Electrochemistry, Electroanalytical Sensor Technology.
This note introduces principles
and mathematical models of electrochemical energy conversion and storage.Topics
covered includes: equivalent circuits, thermodynamics, reaction kinetics,
transport phenomena, electrostatics, porous media, and phase transformations, applications to batteries, fuel cells,
supercapacitors, and electrokinetics.
This note covers the following topics: Fundamental Physical and Chemical
Conceptions, Older Electrochemical Views, The Laws of Avogadro and van't Hoff,
Vapour Pressure of Solutions, Boiling Point and Freezing Point of Solutions,
General Conditions of Equilibrium, Velocity of Reaction, Electrolytes,
Electrolytic dissociation, Conductivity of Electrolytes, Degree of Dissociation
and Dissociation Constant, Conclusions from the Dissociation Theory, Additive
Properties of Solutions, Equilibrium between Several Electrolytes, Calculation
of Electromotive Forces, Calculation of Electromotive Forces, Oxidation and
Reduction Elements, Secondary Elements, Electro-analysis, Development of Heat by
the Electric Current.
This note covers the following topics:
Galvanic cells and electrodes, Cell potentials and thermodynamics, The Nernst
Equation, Applications of the Nernst Equation, Electrochemical energy storage
and conversion, Electrolytic cells and electrolysis.
This note covers the
following topics: Impedance Spectroscopy, Corrosion and Coatings,
Electrochemical Energy Devices, Electrodes and Cells, Instrumentation.
This note covers the following topics: Oxidation-reduction
Reactions, Ohm’s Law, Types of Electrochemical Cells, Tying Electrochemistry to
Thermodynamics, Galvanic Cell and Electrolytic Cells, Anodes and Cathodes, Salt
Bridges, Standard Potentials, Standard Reduction Potentials, The Nernst
Equation.