The objective of this note is to
learn under what conditions the matter changes and to formulate the change in
terms of thermodynamic variables, and also learn the basic principles of
statistical thermodynamics for understanding the molecular motion, chemical
reactions, and kinetics. In this lecture, we first understand the core concepts
of physical chemistry, and apply them to various situations with physical
interpretation.
This
text follows the mainstream core principles of physical chemistry in a way that
highlights statistical thermodynamics with its applications. Starting with the
thermodynamics of ideal gases, it leads to the kinetic theory of gases and
detailed molecular behavior descriptions. The text also enters the domain of
chemical kinetics, describing reaction rates as they relate to many variables.
The book explores surface adsorption and transport phenomena, aiding in the
illustration of the comprehension of molecules in the behavior at the interface
and in motion. The book on physical chemistry was created for higher class
students. The book is a very rigorous approach to physical chemistry with clear
explanations and practical insights into molecular dynamics and thermodynamic
principles.
Author(s): Alberto Otero de la Roza, University of Oviedo
This textbook
takes a practical approach to physical chemistry by providing an application of
the fundamental principles in real settings. The first topics in this textbook
include the first and second laws of thermodynamics, Gibbs free energy, phase
equilibria, chemical equilibrium, electrochemical principles, quantum chemistry,
and statistical mechanics. It dwells on three-dimensional systems and the
time-dependent Schrödinger equation in which quite complex chemical dynamics can
be explained in further detail. It is especially for advanced learners and helps
them achieve theoretical knowledge as well as practical insights into the
behavior of chemical systems and their interactions in various environments.