This book
makes a deep dive into the physical principles underlying electrochemical
processes, mainly focusing on the electrical double layer (EDL), solute
transport, and electrokinetics. In this text, there is coverage of models that
describe the EDL, such as the Gouy-Chapman-Stern model, and extends into more
complex phenomena such as combined mass transport and chemical reactions,
reverse osmosis, and electrodialysis. It also goes into the physics of
electrochemical systems at the microscopic level, both non-Faradaic and Faradaic
processes. The book applies to fields like bioelectrochemistry and environmental
chemistry and even briefly discusses some experimental methods and numerical
modeling used in electrochemical research.
This lecture note provides an exposure into electrochemistry
with all its facets, ranging from the fundamentals like redox reactions and
Faraday's laws to advanced concepts in industrial electrochemistry. Topics range
from equilibrium electrochemistry to electrochemical cells, and from energy
conversion and storage systems like batteries and fuel cells, analytical methods
and sensors, to corrosion protection. The applications of electrochemistry are
also brought into display, be it in the fields of energy storage, corrosion
processes, or latest technologies. Anyone looking to learn about the
electrochemical basis of energy systems and environmental processes will find
this resource indispensable.
This thesis examines the electrochemistry of magnesiumion systems by
modifying the Lewis acidbase pair to improve the stability and performance of
magnesium electrolytes. It specifically focuses on two novel approaches aimed at
improving non-Grignard magnesium electrolytes oxidative stability and reducing
corrosion in stainless steel systems. The work discusses the surface
modification of carbon electrodes and the use of molybdenum-oxo complexes for
proton reduction. It concludes in discussions toward future prospects in
magnesium-ion electrochemistry, especially for high-performance energy storage
systems.
Author(s): Emily G. Nelson, University of
Michigan
This series of lectures deals with
great detail about advanced electrochemical concepts like both Faradaic and non-Faradaic
processes, mass transfer controlled reactions, and electrochemical
thermodynamics. Issues deal with the Butler-Volmer model for electrode kinetics,
liquid junction potentials, and selective electrodes. The note also deals with
the techniques that include sampled current voltammetry and cyclic voltammetry,
and thus one can analyze the quasireversible and irreversible electrode
reactions. This resource is appropriate for more advanced students and
researchers aiming to dive deeper into electrochemical processes and techniques
of analysis.
The book undertakes a comprehensive review of electrochemical sensors with
applications in specific chemical and biosensing fields. It discusses all the
developments in electrochemical and electroanalytical methods and goes about
innovations and improvements in sensor design. In so doing, chapters by
international experts show the various sensor types used in environmental
monitoring, health-related applications, and industrial applications. In
general, this book is highly rich in theoretical principles and practical
applications, and thus makes it excellent reading for practitioners working in
the field of sensor technology and electrochemical analysis.
Author(s): Mohammed Muzibur Rahman and Abdullah Mohammed
Asiri